Pt/Ga-SBA-15 composites synthesis and characterization

Authors

  • Romeo Hernández-Morales Universidad Juárez Autónoma de Tabasco
  • José G. Pacheco Sosa Universidad Juárez Autónoma de Tabasco
  • José Escobar Aguilar INSTITUTO MEXICANO DEL PETRÓLEO
  • J. G. Torres Torres Universidad Juárez Autónoma de Tabasco
  • H. Pérez Vidal Universidad Juárez Autónoma de Tabasco
  • M. A. Lunagómez Rocha Universidad Juárez Autónoma de Tabasco
  • D. de la Cruz Romero Universidad Juárez Autónoma de Tabasco
  • María C. Barrera UNIVERSIDAD VERACRUZANA

DOI:

https://doi.org/10.47566/2020_syv33_1-200301

Keywords:

SBA-15, gallium, platinum, composites, dispersion

Abstract

Pt (0.5, 1 and 1.5 wt%) was impregnated by incipient wetness on SBA-15 and corresponding  Ga-modified (3, 5, 10 and 20 wt%) composites. Gallium nitrate was incorporated directly during the mesoporous siliceous network synthesis. Materials were characterized by N2 physisorption, X-ray diffraction, Fourier transformed infrared spectroscopy, scanning electron microscopy and transmission electron microscopy. SBA-15 had surface area greater than 800 m²/g that decreased by Ga incorporation in binary materials. It seemed that tetrahedral gallium was well-incorporated into mesoporous silica walls. Pt dispersion slightly diminished (as to that on SBA-15) by augmenting Ga concentration in composites. Corresponding pore size maxima shifted to lower diameters (as to that of non-impregnated supports) after platinum loading suggesting Pt crystals inside pores of SBA-15 and Ga-modified carriers. Large cubic platinum crystals were observed over all prepared materials probably due to sintering (during calcining at 500 °C) of metallic particles weakly interacting with the carriers surface. After materials annealing (500 °C under static air) metallic platinum was evidenced (by XRD) pointing out to noble metal reduction that could be facilitated by decomposition of organic remains from Si alkoxide used during supports synthesis which presence was ascertained by FTIR.

Author Biographies

  • Romeo Hernández-Morales, Universidad Juárez Autónoma de Tabasco
    MASTER IN SCIENCE STUDENT
  • José G. Pacheco Sosa, Universidad Juárez Autónoma de Tabasco
    FULL PROFESSOR, CHEMISTRY DEPARTMENT
  • José Escobar Aguilar, INSTITUTO MEXICANO DEL PETRÓLEO
    SENIOR RESEARCHER
  • J. G. Torres Torres, Universidad Juárez Autónoma de Tabasco
    FULL PROFESSOR, CHEMISTRY DEPARTMENT
  • H. Pérez Vidal, Universidad Juárez Autónoma de Tabasco
    FULL PROFESSOR, CHEMISTRY DEPARTMENT
  • M. A. Lunagómez Rocha, Universidad Juárez Autónoma de Tabasco
    FULL PROFESSOR, CHEMISTRY DEPARTMENT
  • D. de la Cruz Romero, Universidad Juárez Autónoma de Tabasco
    FULL PROFESSOR, CHEMISTRY DEPARTMENT
  • María C. Barrera, UNIVERSIDAD VERACRUZANA
    FULL PROFESSOR, CHEMICAL ENGINEERING DEPARTMENT

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— Updated on 2020-03-29

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Vol. 33 (2020)

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Research Papers

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How to Cite

Pt/Ga-SBA-15 composites synthesis and characterization. (2020). Superficies Y Vacío, 33, 200301. https://doi.org/10.47566/2020_syv33_1-200301