Preparation and characterization of degradable compound materials
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Keywords

Polyethylene
Poly (lactic acid)
Maleic anhydride
Mechanical properties
Thermogravimetric analysis
Scanning Electron Microscopy. Polietileno
Poli(ácido láctico)
Anhídrido maléico
Propiedades mecánicas
Análisis termogravimétrico
Microscopia electrónica de barrido.

How to Cite

Rodríguez Félix, D. E., Quiroz Castillo, J. M., Del Castillo Castro, T., Castillo Ortega, M. M., Ramírez Rodríguez, L., García Bedoya, D., & Mendívil Reynoso, T. (2015). Preparation and characterization of degradable compound materials. Superficies Y Vacío, 28(1), 18-24. Retrieved from https://superficiesyvacio.smctsm.org.mx/index.php/SyV/article/view/123

Abstract

Increasing volumes of synthetic polymers are manufactured for various applications, a way to address the problem of the polymer waste is by adding natural occurring polymers to a synthetic polymeric matrix. In this work, it was possible to extrude films of polyethylene (PE) with poly(lactic acid) (PLA) at any weight ratio; however, a range of 10 to 50 wt% PLA was selected.
The results of tensile strength tests demonstrated a strong interaction of the chains of PE and poly (lactic acid) in the presence of 5 wt% of compatibilizer. Thermal analysis showed an improvement in thermal stability of the compatibilized films. SEM images showed a smooth and homogeneous surface in the films, regardless of the presence of the compatibilizer.
The sensitivity to temperature, relative humidity, and solar radiation was evaluated for the films containing a 50 wt% of PLA in the polymeric matrix of PE; this was done through solar degradation experiments.

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References

. G. Singh, H. Bhunia, A. Rajor and V. Choudhary, Polymer Bulletin 66, 939 (2011).

. C. S. Wu, Polymer 46, 147 (2005). [3]. S. J. Huang, Degradable polymers. ISBN: 978-90-481-6091-4 (2002).

. N. T. Dintcheva, S. Al-Malaika, F. P. La Mantia, Polymer Degradation and Stability 94, 1571 (2009).

. H. Balakrishnan, A. Hassan, M.U. Wahit, A.A. Yussuf and S.B.A. Razak. Materials and Design 31, 3289 (2010).

. L. Ashabi, S. H. Jafari, H. A. Khonakdar, L. Haussler, U. Wagenknecht and G. Heinrich Thermochimica Acta 565, 102 (2013).

. D. Garlotta, Journal of Polymers and the Environment 9, 2 (2002).

. K. Athanasiou, G. Niederauer and C. Agrawal, Biomaterials 17, 93 (1996).

. M. Blazewicz, M. Chomyszyn-Gajewska and C. Paluszkiewicz, Journal of Molecular Structure 483, 519 (1999).

. N. Reddy, D. Nama and Y. Yang, Polymer Degradation and Stability 93, 233 (2008).

. M. Omura, T. Tsukegi, Y. Shirai, H. Nishida and T. Endo, Industrial Engineering Chemistry Research 45, 2949 (2006).

. N. Bitinis, R. Verdejo, E. M. Maya, E. Espuche, P. Cassagnau and M. A. Lopez-Manchado, Composites Science and Technology 72, 305 (2012).

. N. Sutivisedsak, H. N. Chengb, M. K. Dowdb, G. W. Selling and A. Biswas A, Industrial Crops and Products 36, 127 (2012).

. J. Zhang and X. Sun X, Biomacromolecules 5, 1446 (2004).

. M. Takatani, K. Ikeda, K. Sakamoto and T. Okamoto, J Wood Sci 54, 54 (2008).

. T. Del Castillo-Castro, M. M. Castillo-Ortega, P. J. Herrera-Franco and D. E. Rodriguez-Felix, Journal of Applied Polymer Science 119, 2895 (2011).

. S. M. Al-Salem, Materials and Design 30, 1729 (2009).

. V. P. Martino, R. Ruseckaite and A. Jimenez, J Thermal Analysis and Calorimetry 86, 707 (2006).

. J. Guan, K.M. Eskridge and M.A. Hanna. Industrial Crops and Products 22, 109 (2005).

. K. Oksman, A.P. Mathew, D. Bondeson and I. Kvien. Composites Science and Technology 66, 2776 (2006).

. A. Copinet, C. Bertrand, S. Govindin, V. Coma and Y. Couturier Y, Chemosphere 55, 763 (2004).

. C. Chuensangjun, C. Pechyen and S. Sirisansaneeyakul, Energy Procedia 34, 73 (2013).

. G. Gorrasi and A. Sorrentino, Polymer Degradation and Stability 95, 963 (2013).

. S. Bocchini, K. Fukushima, A. Di Blasio, A. Fina, A. Frache and F. Geobaldo, Biomacromolecules 11, 2919 (2010).

. M. Gardette, S. Therias, J. L. Gardette, M. Murariu and P. Dubois, Polymer Degradation and Stability 96, 616 (2011).

. M. Day, K. Shaw, D. Cooney, J. Watts and B. Harrigan. Journal of Environmental Polymer Degradation 5, 137 (1997).

. I. Spiridon, O. M. Paduraru, M. F. Zaltariov and R. N. Darie, Industrial and Engineering Chemistry Research 52, 9822 (2013).