The role of Zn-complexing agents in the chemical bath deposition of ZnO and ZnS thin films

Thermodynamic analysis
Equilibrium chemical
ZnS
Thin films deposition
Complexing agents Análisis termodinámico
Equilibrio químico
ZnS
Depósito de películas delgadas
Agentes acomplejantes

Cómo citar

Vargas Rueda, J. A., Alonso, A. R., & Melendez-Lira, M. (2022). The role of Zn-complexing agents in the chemical bath deposition of ZnO and ZnS thin films. Superficies Y Vacío, 35, 221202. https://doi.org/10.47566/2022_syv35_1-221202

Resumen

In order to control the deposition of Zn-related films by chemical bath deposition, the effects of Zn-complexing agent are analyzed. ZnS films were produced by chemical bath deposition technique employing sodium citrate, ethanolamine and Triethanolamine as complexing agents. The deposition conditions for ZnS (ZnO) thin films were obtained through a thermodynamic analysis, using distribution diagrams for molar fraction of Zn complexes. From species distribution diagrams of Zn-ethanolamine, Zn-Triethanolamine and Zn-citrate. It was found that for pH values between 4 and 6 the highest Zn fraction is obtained. The results highlight the importance of complexing agent morphology, while the use of ethanolamine and triethanolamine produce ZnO films due to their high reactivity; the use of sodium citrate produce ZnS films. Deposited ZnS films have a cubic structure, n-type conductivity, resistivity of 8.36×10⁴ ??cm with a 3.75 eV bandgap.

https://doi.org/10.47566/2022_syv35_1-221202

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The role of Zn-complexing agents in the chemical bath deposition of ZnO and ZnS thin films

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