Crystallization of PNIPAM-hydrogel nanospheres inferred by static light scattering
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Reyes Contreras, D., Mayorga Rojas, M., Rojas Ochoa, L., & Haro Pérez, C. (2013). Crystallization of PNIPAM-hydrogel nanospheres inferred by static light scattering. Superficies Y Vacío, 26(3), 79-83. Recuperado a partir de https://superficiesyvacio.smctsm.org.mx/index.php/SyV/article/view/158

Resumen

In this paper we present a kinetic study on crystallization of a colloidal dispersion formed by thermosensitive Poly-NIsopropylacrylamide (PNIPAM) nanospheres. The liquid-crystal transition is induced by decreasing the temperature of the dispersion and the crystallization process is monitored by measuring the evolution of the static structure factor of the dispersion by means of light scattering techniques. The measured static structure factor confirms the formation of a mesoscopic crystal array at the final equilibrium state, which is preceded by two stages: nucleation and crystal growth.
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I. Roland, G. Piel, L. Delattre, B. Evrard, Int. J. Pharm. 263, 85 (2003).

W. Umbach, Progr. Colloid Polym. Sci. 16, 111 (1998).

D. Wirtz, Annu. Rev. Biophys. 38, 301 (2009).

N. Nijenhuis, D. Mizuno, J. A. Spaan, C. F. Schmidt, J. R. Soc. Interface 73, 1733 (2012).

W. C. Ruder, C.-P. D. Hsu, B. D. Edelman Jr., R. Schwartz, P. R. LeDuc, App. Phys. Lett. 101, 063701 (2012)

S. Martins, B. Sarmento, D. C. Ferreira, E. B Souto, Int. J. Nanomedicine 2, 595 (2007).

R. Mezzenga, P. Fischer, Rep. Prog. Phys. 76, 1 (2013)

J. P. K. Doye, A. A. Louis, I. C. Lin, L. R. Allen, E. G. Noya, A. W. Wilber, H. C. Kok, R. Lyus, Phys. Chem. Chem. Phys. 9, 2197 (2007).

R. Kretzschmar, T. Schäfer, Elements 1, 205 (2005).

S. Gourianova, N. Willenbacher, M. Kutschera, Langmuir E 40, 0501379 (2005).

D. Marksteiner, S. Wasser, W. Schartl, Langmuir 25, 12843 (2009).

P. G. Vekilov, Cryst. Growth Des. 4, 671 (2004).

J. F. Lutsko, G. Nicolis, Phys. Rev. Lett. 96, 046102 (2006)

V. J. Anderson, H. N. W. Lekkerkerker, Nature 416, 811 (2002).

L. F. Filobelo, O. Galkin, P.G. Vekilov, J. Chem. Phys. 123, 014904 (2005).

C. Haro-Pérez, L. F. Rojas-Ochoa, V. Trappe, R. Castañeda-Priego, J. Estelrich, M. Quesada-Pérez, J. Callejas- Fernández, and R. Hidalgo-Álvarez, “Structural and Functional Properties of colloidal systems” CRC Press, Taylor and Francis Group, ISBN: 978-1-4200-8446-7, Vol. 146, 77-91 (2009).

M. Q. Pérez, A. M. Molina, F. G. González, R. H. Álvarez, Mol. Phys. 18, 3029 (2002).

M. A. Bevan, J. A. Lewis, P. V. Braun, P. Wiltzius, Langmuir 20, 7045 (2004).

M. Mayorga, D. O. González, L. R. Salazar, I. S. Holek, J.M. Rubi, Physica A 388, 1973 (2009).

D. Frenkel, Nature Mater. 5, 85 (2006).

S. G. Mitra, T. Cai, D. Diercks, Z. Hu, J. Roberts, J. Dahiya, N. Mills, D. Hynds and S. Ghosh, Polymers 3, 1243 (2011).

I. Galaev, B. Mattiason, Smart Polymers: Applications in Biotechnology and Biomedicine, Taylor & Francis Group, 247 LLC, (USA, 2008).

A. Neogi, H. Everitt, H. Morkoç, T. Kuroda, A. Tackeuchi; IEEE Transactions on Nanotechnology 2, 1 (2003).

T. Hellweg, C. D. Dewhurst, E. Brükner, K. Kratz, W. Eimer, Colloidal Polym. Sci. 278, 972 (2000).

B. W. Garner, T. Cai, S. Ghosh, Z. Hu, A. Neogi, Appl. Phys. Express 2, 057001 (2009).

H. Gao, W. Yang, K. Min, L. Zha, C. Wang, S. Fu, Polymer 46, 1087 (2005).

B. Y. Zhang, W. D. He, L. Y. Li, X. L. S., W. T. L., K. R. Zhang, J. Polym. Sci. Part A: Polym. Chem 48, 3604 (2010).

S. Tang., Z. Hu, Z. Cheng, J. Wu, Langmuir 20, 8858 (2004).

B. W. Garner, T. Cai, Z. Hu, M. Kim, A. Neogi, Applied Physics Express 2, 075001 (2009).

S. G. Mitra, T. Cai, S. Ghosh, A. Neogi, Z. Hu, N. Mills, Mater. Res. Soc. Symp. Proc. 1064, 6 (2008).

T. R. Hoare, D. S. Kohane, Polymer 49, 1993 (2008).

S. Amin, S. Rajabnezhad, K. Kohli, Sci. Res. Essays 3, 1175 (2009).

S. Giray, T. Bal, A. M. Kartal, S. Kızılel, C. Erkey, J. Biomed. Mater. Res. A. 100, 1307 (2012).

M. Heskins and J.E. Guillet, J Macromol. Sci. Phys. 2, 1441 (1968).

J. G. H. Joosten, J. L. McCarthy, P. N. Pusey, Macromolecules 24, 6690 (1991).

C. Urban, P. Schurtenberger, J. Colloid Interface Sci. 207, 150 (1998).

J. Berne, Bruce, Pecora Robert, Dynamic Light Scattering with applications to chemistry, biology and Physics, Dover Publications, (Canada, 2000).

J. P. Hansen, L. Verlet, Phys. Rev. 184, 151 (1969).

G. Nägele, Phys. Reports 272, 215 (1996).

J. L. Harland, W. van Megen, Phys. Rev. E 55, 3054 (1997).

W. van Megen, S. M. Underwood, J. Chem. Phys. 88, 7841 (1988).

S. Tang, Z. Hu, Z. Cheng, J. Wu, Langmuir 20, 8858 (2004).

S. Iacopini, T. Palberg, Hans J. Schöpe, J. Chem. Phys. 130, 084502 (2009).